Abstract: At present,the chemiluminescence analysis is a novel and highly sensitive analytical technique for trace analysis and makes feature a of fast analytical speed,simple instrumentation and easiness for automation.It has found a wide application not only in the organic technology,medicine,food testing,but also in environmental monitoring and material science.The luminescent systems used in the chemiluminescence is increasing greatly.Based on summarizing a great number of assays,this paper introduces many newly rising chemiluminescence systems builted in resent years and their application.It also gives a review of chemiluminescence analysis in detail.