吡咯等离子体聚合产物分析
Analysis of Plasma Polymerization Product of Pyrrole
-
摘要: 用色谱-质谱、裂解色谱-质谱、电子自旋共振、红外光谱及元素分析等方法鉴定了吡咯等离子体聚合过程中气相冷凝物和聚合物的组成,根据分析结果提出了吡咯等离子体聚合的自由基反应历程.Abstract: This paper reports the identification of polymer and gaseous condensate from plasma polymeization of pyrrole by means of gas chromatography-mass spectrometry,paramagentic resonance,infrared spectroscopy and elementary analysis.According to the analytical results the free radical mechanism of the plasma polymerization for pyrrole is suggested.