离子色谱法快速测定氯化钾中微量溴离子和硫酸根离子

Determination of Trace Br and SO4 2− in Potassium Chloride by Ion Chromatography

  • 摘要: 建立了离子色谱-抑制型电导快速检测氯化钾中微量溴离子和硫酸根离子的方法. 在优化的色谱条件下,Br和SO4 2−分别在0.05~10 mg/L质量浓度范围内线性关系良好(相关系数r分别为0.995 1、0.996 2),方法检出限分别为0.029、0.020 mg/L. 氯化钾中Br和SO4 2−的加标回收率在93.7%~99.0%范围内. 方法具有线性范围好、易于操作、灵敏度高等特点,可作为氯化钾中快速检测Br 和SO4 2− 的质量控制方法.

     

    Abstract: A method for rapid detection of trace bromide and sulfate ions in potassium chloride by ion chromatography with suppressed conductivity has been established. The calibration curves of Br and SO4 2− showed good linearity in the range of 0.05~10 mg/L (r was 0.995 1, 0.996 2, respectively). The detection limits of Br and SO4 2− were 0.029 mg/L and 0.020 mg/L, respectively. The recoveries of Br and SO4 2− in potassium chloride ranged from 93.7% to 99.0%. The method is of a good linear range, easy operation and high sensitivity, can be used as the quality control method for the rapid detection of Br and SO4 2− in potassium chloride.

     

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